REVERSIBLE INTRAMOLECULAR BASE STABILIZATION OF A LOW-COORDINATE SILICON ATOM IN THE SILANEDIYL COMPLEX [(ORTHO-ME2NCH2C6H4)2SI=CR(CO)5]

被引：80

作者：

PROBST, R ^{[1
]}

LEIS, C ^{[1
]}

GAMPER, S ^{[1
]}

HERDTWECK, E ^{[1
]}

ZYBILL, C ^{[1
]}

AUNER, N ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST ANORGAN CHEM,LICHTENBERGSTR 4,W-8046 GARCHING,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 09期

关键词：

D O I：

10.1002/anie.199111321

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Si-N distance in 1 lies well outside the range of covalence. The presence of a loose donor, bond is also found by NMR spectroscopic findings in solution: above 58-degrees-C the amino ligand detaches reversibly from the silicon with formation of the donor-free complex 2. [GRAPHICS]

引用

页码：1132 / 1134

页数：3

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