PREPARATIONS AND REACTIONS OF TRIFLUOROMETHYLTHIOCOPPER

被引：32

作者：

MUNAVALLI, S ^{[1
]}

ROSSMAN, DI ^{[1
]}

ROHRBAUGH, DK ^{[1
]}

FERGUSON, CP ^{[1
]}

HSU, FL ^{[1
]}

机构：

[1] USA,CTR CHEM RES DEV & ENGN,ABERDEEN PROVING GROUND,MD 21010

来源：

HETEROATOM CHEMISTRY | 1992年 / 3卷 / 02期

关键词：

D O I：

10.1002/hc.520030216

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Trifluoromethylthiocopper, a versatile reagent for the introduction of the trifluoromethylthio group into organic compounds, has been prepared in a crystalline form. The thiyl radicals, generated in situ from this precursor, cause the cleavage of the S-S bond of di- and trisulfides to give unsymmetrical di- and trisulfides. Unsymmetrical n-butyl trifluoromethyl disulfide is formed by the cleaveage of the C-S bond of n-butyl sulfide.

引用

页码：189 / 192

页数：4

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