EXCESS VOLUMES AND REFRACTIONS AND LIQUID-LIQUID EQUILIBRIA OF THE TERNARY-SYSTEM WATER PLUS ETHANOL PLUS HEXYL ACETATE

被引:20
作者
ARCE, A
BLANCO, A
SOTO, A
SOUZA, P
VIDAL, I
机构
[1] Chemical Engineering Department, University of Santiago de Compostela
关键词
D O I
10.1016/0378-3812(93)85036-L
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities, refractive indices, excess molar volumes and excess molar refractions at 25-degrees-C, and liquid-liquid equilibrium (LLE) data at 25, 35 and 45-degrees-C, are reported for the system water + ethanol + hexyl acetate. NRTL and UNIQUAC equations have been fitted to the experimental data, and the sensitivity of the correlation to changes in the composition of the phases in equilibrium has been analysed. The validity of the parameters obtained from the ternary system data for representation of the binary systems was also assessed.
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页码:347 / 364
页数:18
相关论文
共 10 条
[1]   STATISTICAL THERMODYNAMICS OF LIQUID-MIXTURES - NEW EXPRESSION FOR EXCESS GIBBS ENERGY OF PARTLY OR COMPLETELY MISCIBLE SYSTEMS [J].
ABRAMS, DS ;
PRAUSNITZ, JM .
AICHE JOURNAL, 1975, 21 (01) :116-128
[2]  
Akhnazarova S., 1982, EXPT OPTIMIZATION CH
[3]   LIQUID LIQUID EQUILIBRIA OF THE SYSTEM WATER + ACETIC-ACID + METHYL ISOPROPYL KETONE BETWEEN 25-DEGREES-C AND 55-DEGREES-C [J].
CORREA, JM ;
BLANCO, A ;
ARCE, A .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1989, 34 (04) :415-419
[4]   MULTIPLE SOLUTIONS, FLEXIBILITY AND LIMITATIONS OF APPLICATION OF NRTL FORMULA FOR MODELS AND PRECALCULATION OF VAPOR-LIQUID-EQUILIBRIA [J].
GREINER, E ;
TAUBERT, K ;
DONTH, E .
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1976, 41 (05) :1459-1470
[5]   CALCULATION OF MULTICOMPONENT LIQUID-LIQUID EQUILIBRIUM WITH RENONS AND BLACKS ACTIVITY EQUATIONS [J].
GUFFEY, CG ;
WEHE, AH .
AICHE JOURNAL, 1972, 18 (05) :913-&
[6]   UNIFAC PARAMETER TABLE FOR PREDICTION OF LIQUID-LIQUID EQUILIBRIA [J].
MAGNUSSEN, T ;
RASMUSSEN, P ;
FREDENSLUND, A .
INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1981, 20 (02) :331-339
[7]  
Novak J.P., 1987, LIQUID LIQUID EQUILI
[8]   LOCAL COMPOSITIONS IN THERMODYNAMIC EXCESS FUNCTIONS FOR LIQUID MIXTURES [J].
RENON, H ;
PRAUSNITZ, JM .
AICHE JOURNAL, 1968, 14 (01) :135-+
[9]  
Sorensen J. M., 1980, THESIS TU DENMARK LY
[10]   PREDICTION OF VAPOR LIQUID EQUILIBRIUM FROM TERNARY LIQUID LIQUID EQUILIBRIUM DATA [J].
YEE, D ;
SIMONETTY, J ;
TASSLOS, D .
INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1983, 22 (01) :123-129