ANALYSIS OF THE DISORDER OCCURRING IN THE CRYSTAL-STRUCTURE OF SYNDIOTACTIC POLYPROPYLENE

被引：77

作者：

AURIEMMA, F ^{[1
]}

DEROSA, C ^{[1
]}

CORRADINI, P ^{[1
]}

机构：

[1] UNIV NAPOLI FEDERICO II,DIPARTIMENTO CHIM,VIA MEZZOCANNONE 4,I-80134 NAPLES,ITALY

来源：

MACROMOLECULES | 1993年 / 26卷 / 21期

关键词：

D O I：

10.1021/ma00073a029

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Some possible kinds of disorder in the packing of chains of syndiotactic polypropylene, compatible with the maintenance of crystalline long-range order, are discussed and the corresponding models are described. The diffraction intensities at appropriate points or lines of the reciprocal lattice are calculated for the various models; experimental observations of the intensity lowering of some reflections and the appearance of haloes are explained with the models in a semiquantitative way. The possible connection of some kinds of disorder with the presence of configurational defects along the chains is discussed.

引用

页码：5719 / 5725

页数：7

共 16 条

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