SYNTHESIS OF ACTIVE SITES FOR ALKENE METATHESIS REACTION ON MOLYBDENUM OXIDE FILMS BY THE REACTION WITH ALKYLIDENE RADICALS

被引：10

作者：

Kazuta, Mayumi ^{[1
]}

Tanaka, Ken-ichi ^{[1
]}

机构：

[1] Univ Tokyo, Inst Solid State Phys, Minato Ku, Tokyo 106, Japan

来源：

CATALYSIS LETTERS | 1988年 / 1卷 / 1-3期

关键词：

CATALYSIS - FILMS - Preparation - MOLYBDENUM COMPOUNDS - Sublimation;

D O I：

10.1007/BF00765347

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A super active catalyst (T.F. = 0.2 similar to 0.3) for alkene metathesis reaction was prepared by coordinating CH2 radicals onto sublimed molybdenum oxide films, where the radicals were prepared by the reaction of CH2I2 with Al or Mg metals deposited near the oxide film.

引用

页码：7 / 10

页数：4

共 6 条

[1] REACTION OF ATOMICALLY CLEAN ALUMINUM AND CHEMICALLY MODIFIED ALUMINUM WITH ALKYL-HALIDES
CHEN, JG
BEEBE, TP
CROWELL, JE
YATES, JT
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (06) : 1726 - 1729
[2] THE GENERATION OF METHYLENE FROM CH2I2 ON AL SURFACES
DOMEN, K
CHUANG, TJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (17) : 5288 - 5289
[3] PREPARATION OF VERY ACTIVE MOLYBDENUM OXIDE-FILMS FOR USE IN THE ALKENE METATHESIS REACTION
KAZUTA, M
TANAKA, KI
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (08) : 616 - 617
[4] INTRINSIC REACTIVITY OF MAGNESIUM SURFACES TOWARD METHYL-BROMIDE
NUZZO, RG
DUBOIS, LH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (11) : 2881 - 2886
[5] CATALYSIS CONTROLLED BY THE CONSTITUTION OF ACTIVE-SITES
TANAKA, K
[J]. ADVANCES IN CATALYSIS, 1985, 33 : 99 - 158
[6] SUPER ACTIVE CATALYSTS, MOO3 AND MOO3-X-BETA-TIO2 ACTIVATED WITH SNME4, FOR A STRUCTURE RETAINING ALKENE METATHESIS
TANAKA, K
TANAKA, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (12) : 748 - 749

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