AUTOXIDATION OF METHOXYTOLUENE IN ACETIC-ACID - ELECTROCHEMICAL ASSISTANCE OF THE CATALYTIC EFFECT OF COBALT

被引：9

作者：

FALGAYRAC, G ^{[1
]}

SAVALL, A ^{[1
]}

机构：

[1] UNIV TOULOUSE 3,GENIE CHIM & ELECTROCHIM LAB,CNRS,URA 192,F-31062 TOULOUSE,FRANCE

来源：

CATALYSIS TODAY | 1995年 / 24卷 / 1-2期

关键词：

D O I：

10.1016/0920-5861(95)00018-B

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Liquid phase autoxidation of p-methoxytoluene to p-anisaldehyde in water-acetic acid medium (10-90% vol.) using cobalt acetate as a catalyst has been investigated under or not electrolysis between two graphite electrodes. The rate of formation of anisaldehyde is strongly increased under electrolysis condition: the maximum anisaldehyde yield occurs at t=70 min whereas this maximum is reached only after t=5 h 30 min without electrolysis.

引用

页码：189 / 194

页数：6

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