SOLUBILITY AND REACTIONS OF PERCHLORYL FLUORIDE IN WATER

被引：11

作者：

CADY, GH

机构：

[1] Department of Chemistry, University of Washington, Seattle

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1978年 / 11卷 / 3-4期

关键词：

D O I：

10.1016/S0022-1139(00)82443-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Perchloryl fluoride (CℓO3F) when dissolved in water reacts very slowly with the solvent. The solubility in water at one atmosphere pressure and temperatures up to 40°C is given by the equation, solubility (mol/ℓ) = 6.387 x 10-8 exp 6852/RT. The following reactions have been studied to learn their rate laws and rate constants: CℓO3F + 2I- = I2 + F- + CℓO3- CℓO3F + 2OH- = CℓO4- + F- + H2O CℓO3F + 3NH3(aq) = 2NH4+ + HNCℓO3- + F- CℓO3F + H2O = CℓO4- + F- + 2H+ At temperatures near O°C, perchloryl fluoride and water readily form a solid clathrate hydrate of highly variable composition. The observed minimum ratio of H2O to CℓO3F in the solid is about 7.75. © 1978.

引用

页码：225 / 241

页数：17

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