REACTIONS OF BENZYL AND PHENYL RADICALS WITH FLUORENE AND OF BENZYL RADICALS WITH PYRENE

被引：4

作者：

BASS, KC

TAYLOR, GM

机构：

[1] Department of Chemistry, The City University, London

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 03期

关键词：

D O I：

10.1039/j39690000508

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Benzyl radicals, generated by the pyrolysis of dibenzylmercury, react with fluorene to give 9-benzylfluorene, 9,9-dibenzylfluorene, and 9,9′-bifluorenyl. Phenyl radicals, generated by the pyrolysis of diphenylmercury, react with fluorene to give 9-phenylfluorene and 9,9′-bifluorenyl. Homolytic benzylation of pyrene gives 1-benzylpyrene and 1,1′-bipyrenyl. The mechanisms for the formation of the products are discussed.

引用

页码：508 / &

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