MOLECULAR COMPLEXES BETWEEN IODINE CYANIDE AND ORGANOPHOSPHORYL COMPOUNDS

被引：17

作者：

DAHL, R

KLABOE, P

GRAMSTAD, T

机构：

[1] Department of Chemistry, University of Oslo

[2] Norwegian Defense Research Establishment, Division of Toxicology Kjeller

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY | 1969年 / A 25卷 / 01期

关键词：

D O I：

10.1016/0584-8539(69)80187-X

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The formation constants (Kc), the enthalpy of formation (ΔH°) and the spectral shifts of the P-O stretching band (ΔνPO) and the C-I stretching band (ΔνCI) have been determined for the 1:1 complexes between iodine cyanide and 15 organophosphoryl compounds in benzene solution. Linear relationships have been observed between log Kc, and (ΔνCI). The present complexes have been compared with those formed between organophosphoryl compounds with iodine and phenol and various correlations in donor-acceptor interactions have been discussed. © 1969.

引用

页码：207 / &

共 24 条

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