PREPARATION OF THE CLASSICAL RARE EARTH(II) CHLORIDES IN SOLUTION

被引：20

作者：

ROSSMANITH, K

机构：

[1] Institut für Anorganische Chemie, Universität Wien, Wien

来源：

MONATSHEFTE FUR CHEMIE | 1979年 / 110卷 / 01期

关键词：

Europium(II) chloride; Rare earth(II) chlorides (classical); Samarium(II) chloride; Ytterbium(II) chloride·THF;

D O I：

10.1007/BF00903752

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using the reduction of the trichlorides by lithium metal/naphthalene in tetrahydrofurane (THF), SmCl2 and EuCl2 were prepared in solventfree state, very sparingly soluble in THF. The reduction of YbCl3, combined with extraction to eliminate the oxide chloride content, yielded the compound YbCl2·THF, much more soluble in THF than YbCl3. © 1979 Springer-Verlag.

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页码：109 / 114

页数：6

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