METHYL-METHACRYLATE POLYMERIZATION AT HIGH CONVERSION .3. EFFECT OF A CHAIN-TRANSFER AGENT

被引：5

作者：

ABUIN, E

LISSI, EA

机构：

来源：

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY | 1979年 / A13卷 / 08期

关键词：

D O I：

10.1080/00222337908056706

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Bromoform delays the onset of the gel effect of MMA and decreases the acceleration rate in the autoaccelerated region. The first effect can be quantitatively related to the decrease in molecular weight of the produced polymer. The decrease in acceleration shows the dependence of the termination rate constant, in the accelerated region, on the mean size of the growing macroradicals. © 1979, Taylor & Francis Group, LLC. All rights reserved.

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页码：1147 / 1155

页数：9

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