PICOSECOND TIME RESOLVED FLUORESCENCE SPECTROSCOPY STUDY OF AGGREGATION OF PORPHYRIN DERIVATIVE MN(3,4,5-OMETPP)CL

被引：5

作者：

CHEN, JT

YU, ZX

机构：

[1] Institute for Lasers and Spectroscopy, Physics Department, Zhongshan University, Guangzhou

来源：

APPLIED PHYSICS B-PHOTOPHYSICS AND LASER CHEMISTRY | 1990年 / 50卷 / 04期

关键词：

20;

D O I：

10.1007/BF00325065

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

The picosecond time-resolved fluorescence spectrum I(λ, t) of the porphyrin derivative Mn(3,4,5-OMeTPP)Cl is measured. Experiments show that the fluorescence relaxation of the concentrated sample solution is composed of a fast (ps), a moderately fast (100 ps) and a slow (ns) decay process. Furthermore, the fluorescence spectra for various times after excitation have different shapes. Detailed analysis shows that the fluorescence is composed of three components with different relaxation times and spectrum shapes. The three components are attributed to monomers, dimers, and aggregates respectively. © 1990 Springer-Verlag.

引用

页码：313 / 318

页数：6

共 20 条

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[2]

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