PI/SIGMA EQUILIBRIA IN METAL-COMPLEXES OF ORGANIC CARBONYL-COMPOUNDS - SYNTHESIS AND STRUCTURE OF CHIRAL RHENIUM COMPLEXES [(ETA-5-C5H5)RE(NO)(PPH3)(O = CHAR)]X

被引：43

作者：

MENDEZ, NQ ^{[1
]}

ARIF, AM ^{[1
]}

GLADYSZ, JA ^{[1
]}

机构：

[1] UNIV UTAH,DEPT CHEM,SALT LAKE CITY,UT 84112

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 12期

关键词：

D O I：

10.1002/anie.199014731

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

pi/sigma-ratios of > 96: < 4 to 15:85 (at 299 K) occur in the complexes 1, depending on the aryl substituents. Aside from this strong electronic effect, marked solvent and temperature effects could also be detected. These findings are of great importance for an understanding of the bonding behavior of adducts of carbonyl compounds and metal-complex fragments.

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页码：1473 / 1474

页数：2

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