CYCLO-AS8 AS COMPLEX LIGAND

被引：23

作者：

SCHERER, OJ

WINTER, R

HECKMANN, G

WOLMERSHAUSER, G

机构：

[1] Fachbereich Chemie, Universität Kaiserslautern, W-6750, Erwin-Schrödinger-Strasse

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 07期

关键词：

D O I：

10.1002/anie.199108501

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The arsenic analogue of cyclooctatetraene cyclo-As8 can be stabilized as a strongly distorted, puckered eight-membered ring in a complex of niobium (1; each Nb atom also bears a 1,3-di-tert-butylcyclopentadienyl ligand). Complex 1 reacts with [Cr(CO)5(thf)] to form a trinuclear Nb2Cr cluster.

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页码：850 / 852

页数：3

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