EFFECT OF INDISTINGUISHABLE NUCLEI ON PRODUCT ROTATIONAL DISTRIBUTIONS - D+DI-]D2+I

被引：14

作者：

RINNEN, KD

KLINER, DAV

BUNTINE, MA

ZARE, RN

机构：

[1] Department of Chemistry, Stanford University, Stanford

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 169卷 / 05期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(90)87061-U

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A marked population alternation between adjacent rotational levels is observed for the D2(ν=1, J) product of the D+DI→D2+I reaction, analogous to that reported for the H+HI→H2+I reaction (P.M. Aker, G.J. Germann, and J.J. Valentini, J. Chem. Phys. 90 (1989) 4795; D.A.V. Kliner, K.-D. Rinnen and R.N. Zare, J. Chem. Phys. 90 (1989) 4625). These alternations result from the indistinguishability of the D (H) nuclei in the D+DI (H+HI) reaction. The magnitude of the alternations indicates that there are no symmetry constraints on the reaction complex aside from nuclear exchange symmetry (conserved nuclear spin-statistics (CNSS) condition). © 1990.

引用

页码：365 / 371

页数：7

共 36 条

[11] PHOTOFRAGMENTATION DYNAMICS OF FORMALDEHYDE - H2(V,J) DISTRIBUTIONS [J].