BATCH INJECTION-ANALYSIS WITH THE ROTATING-DISK ELECTRODE

被引：16

作者：

CHEN, LA ^{[1
]}

WANG, J ^{[1
]}

ANGNES, L ^{[1
]}

机构：

[1] NEW MEXICO STATE UNIV, DEPT CHEM, LAS CRUCES, NM 88003 USA

来源：

ELECTROANALYSIS | 1991年 / 3卷 / 08期

关键词：

D O I：

10.1002/elan.1140030809

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The use of the rotating disk electrode (RDE) for batch injection analysis (BIA) is illustrated. The technique involves injections of microliter samples into a large-volume blank solution, at a fixed location below the disk center. Transient response peaks-similar to those of flow injection analysis-are observed, reflecting the transport of the sample plug toward and away from the RDE. The effects of various experimental variables on the BIA/RDE operation are described. Injection rates of several thousand samples per hour can be achieved, with relative standard deviations of 1-3%, and detection limits at the micromolar (ng) level.

引用

页码：773 / 776

页数：4