KNOTTEDNESS IN RING POLYMERS

被引:188
作者
KONIARIS, K [1 ]
MUTHUKUMAR, M [1 ]
机构
[1] UNIV MASSACHUSETTS, DEPT POLYMER SCI & ENGN, AMHERST, MA 01003 USA
关键词
D O I
10.1103/PhysRevLett.66.2211
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We represent ring polymers in free space with the rod-bead model and show through unbiased computer simulations that the probability of observing a trivial self-entanglement (P) has a decreasing exponential dependence on the contour length (N) of the polymer, or that P = exp(-N/N0). The characteristic length (N0) varies by many orders of magnitude depending on chain flexibility and solvent quality. We also suggest that sufficiently large knots are always composite, not prime.
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页码:2211 / 2214
页数:4
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