NOVEL HEAD-TO-TAIL ALKYL-ALKENE OR ALKENE-ALKENE COUPLING VIA ZIRCONIUM-CATALYZED REACTION OF ALKYLMAGNESIUM DERIVATIVES WITH MONOSUBSTITUTED ALKENES

被引：36

作者：

ROUSSET, CJ

NEGISHI, EI

SUZUKI, N

TAKAHASHI, T

机构：

[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

[2] INST MOLEC SCI,COORDINAT CHEM LAB,OKAZAKI,AICHI 444,JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 15期

关键词：

D O I：

10.1016/0040-4039(92)88115-L

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of monosubstituted alkenes with alkylmagnesium derivatives catalyzed by Cp2ZrCl2 or related zirconocene derivatives provides head-to-tail alkyl-alkene or alkene-alkene coupling products, approximately 50% of which are 2,5-dialkyl-4-pentenylmagnesium halides.

引用

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页码：1965 / 1968

页数：4

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