CIS-DERIVED AND TRANS-DERIVED CHAIN STACKING IN BIS(HEXAFLUOROACETYLACETONATO)METAL(II) TETRAMETHYLPYRAZINE COMPLEXES

被引：11

作者：

ADAMS, H ^{[1
]}

BAILEY, NA ^{[1
]}

FENTON, DE ^{[1
]}

KHALIL, RA ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

INORGANICA CHIMICA ACTA | 1993年 / 209卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)84980-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of metal(II) hexafluoroacetylacetonates (meta]=Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II)) with tetramethylpyrazine is reported. The X-ray crystal structures of [Mn(hfac)2]2(tmp)3.4H2O and Co(hfac)2(tmp).4H2O are reported and reveal the formation of chain polymers through second sphere cis- and trans-derived stacking, respectively.

引用

页码：55 / 60

页数：6

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