A DIRUTHENIUM DILITHIUM COMPLEX CONTAINING 4 DIFFERENT BONDING TYPES OF TETRAMETHYLENESULFOXIDE LIGANDS

被引：11

作者：

JASWAL, JS

YAPP, DTT

RETTIG, SJ

JAMES, BR

SKOV, KA

机构：

[1] UNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER V6T 1Z1,BC,CANADA

[2] BRITISH COLUMBIA CANC RES CTR,VANCOUVER V5Z 1L3,BC,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 20期

关键词：

D O I：

10.1039/c39920001528

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tetranuclear complex [Br6(tmso)2Ru2(mu2-tmso)2(mu3-tmso)2Li2(tmso)2] (tmso = tetramethylenesulfoxide; s and o imply sulfur- and oxygen-bonded sulfoxide, respectively) has been synthesized; four types of coordinated tmso are present, including a unique mu3-type.

引用

收藏

页码：1528 / 1529

页数：2

相关论文

共 16 条

[1] SYNTHESIS, MOLECULAR-STRUCTURE, AND CHEMICAL BEHAVIOR OF HYDROGEN TRANS-BIS(DIMETHYL SULFOXIDE)TETRACHLORORUTHENATE(III) AND MER-TRICHLOROTRIS(DIMETHYL SULFOXIDE)RUTHENIUM(III) - THE 1ST FULLY CHARACTERIZED CHLORIDE DIMETHYL-SULFOXIDE RUTHENIUM(III) COMPLEXES [J].

ALESSIO, E ;

BALDUCCI, G ;

CALLIGARIS, M ;

COSTA, G ;

ATTIA, WM ;

MESTRONI, G .

INORGANIC CHEMISTRY, 1991, 30 (04) :609-618

[2] SYNTHESIS AND CHARACTERIZATION OF NEW HALOGEN TETRAMETHYLENE SULFOXIDE-RUTHENIUM(II) AND RUTHENIUM(III) COMPLEXES - CRYSTAL-STRUCTURE OF CIS-DICHLOROTETRAKIS(TETRAMETHYLENE SULFOXIDE)RUTHENIUM(II) AND HYDROGEN TRANS-BIS(TETRAMETHYLENE SULFOXIDE)TETRACHLORORUTHENATE(III) [J].

ALESSIO, E ;

MILANI, B ;

MESTRONI, G ;

CALLIGARIS, M ;

FALESCHINI, P ;

ATTIA, WM .

INORGANICA CHIMICA ACTA, 1990, 177 (02) :255-265

[3] THE SYNTHESIS OF RUBR2(DMSO)3 REVISITED - A MIXTURE OF LI[FAC-RUCLNBR3-N(DMSO)3] ISOMERS (N=0-3) IS THE REACTION-PRODUCT [J].

ALESSIO, E ;

MILANI, B ;

CALLIGARIS, M ;

BRESCIANIPAHOR, N .

INORGANICA CHIMICA ACTA, 1992, 194 (01) :85-91

[4] CIS-DIHALOTETRAKIS(DIMETHYL SULFOXIDE)RUTHENIUM(II) AND TRANS-DIHALOTETRAKIS(DIMETHYL SULFOXIDE)RUTHENIUM(II) COMPLEXES (RUX2(DMSO)4, X = CL, BR) - SYNTHESIS, STRUCTURE, AND ANTITUMOR-ACTIVITY [J].

ALESSIO, E ;

MESTRONI, G ;

NARDIN, G ;

ATTIA, WM ;

CALLIGARIS, M ;

SAVA, G ;

ZORZET, S .

INORGANIC CHEMISTRY, 1988, 27 (23) :4099-4106

[5] EFFECTS OF HALIDE (X) AND SULFOXIDE (R2SO) REPLACEMENT WITHIN THE RUTHENIUM(II) NITROIMIDAZOLE COMPLEXES, RUX2(R2SO)M (NITROIMIDAZOLE)N, M = 1-3, N = 1 OR 2 - THEIR CHARACTERIZATION, SOLUTION CHEMISTRY, RADIOSENSITIZING ACTIVITY, AND RELATED PROPERTIES [J].

CHAN, PKL ;

JAMES, BR ;

FROST, DC ;

CHAN, PKH ;

HU, HL ;

SKOV, KA .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1989, 67 (03) :508-516

[6]

FENTON DE, 1987, COMPREHENSIVE COORDI, V3, P1

[7] THE STRUCTURAL REFORMULATION OF [RU2CL4(ME2SO)5] [J].

HEATH, GA ;

LINDSAY, AJ ;

STEPHENSON, TA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (12) :2429-2932

[8] RUTHENIUM(II)-DIMETHYL SULFOXIDE COMPLEXES WITH NITROGEN LIGANDS - SYNTHESIS, CHARACTERIZATION AND SOLUTION CHEMISTRY - THE CRYSTAL-STRUCTURES OF CIS,FAC-RUCL2(DMSO)3(NH3) AND TRANS,CIS,CIS-RUCL2(DMSO)2(NH3)2.H2O [J].

HENN, M ;

ALESSIO, E ;

MESTRONI, G ;

CALLIGARIS, M ;

ATTIA, WM .

INORGANICA CHIMICA ACTA, 1991, 187 (01) :39-50

[9] SULFUR-BONDED SULFOXIDE COMPLEXES OF RHODIUM(III) AND RHODIUM(I) [J].

JAMES, BR ;

MORRIS, RH .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1980, 58 (04) :399-408

[10] RUTHENIUM(III) COMPLEXES CONTAINING DIMETHYLSULFOXIDE OR DIMETHYLSULFIDE LIGANDS, AND A NEW ROUTE TO TRANS-DICHLOROTETRAKIS(DIMETHYLSULFOXIDE)RUTHENIUM(II) [J].

JASWAL, JS ;

RETTIG, SJ ;

JAMES, BR .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1990, 68 (10) :1808-1817