CATALYTIC LIQUID-PHASE FLUORINATION OF TETRACHLORETHENE (PCE) WITH TITANIUM ANTIMONY MIXED HALIDES

被引：2

作者：

BATIOT, C ^{[1
]}

BRUNET, S ^{[1
]}

BARRAULT, J ^{[1
]}

BLANCHARD, M ^{[1
]}

机构：

[1] ESIP,CATALYSE LAB,40 AVE RECTEUR PINEAU,F-86022 POITIERS,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 07期

关键词：

D O I：

10.1039/c39940000867

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new catalyst consisting of a TiCl4-SbCl5 mixture with a molar composition Sb: Ti = 4: 1 makes possible the fluorination of tetrachlorethene with liquid HF at 90-degrees-C.

引用

页码：867 / 867

页数：1

共 4 条

[1] HALIDE ABSTRACTION BY ANTIMONY(V) - A CONVENIENT ROUTE TO ANTIMONATE(V) SALTS INVOLVING CATIONIC TRANSITION-METAL SPECIES - CRYSTAL AND MOLECULAR-STRUCTURE OF FAC[TICL3(MECN)3][SBCL6] [J].

CLAIRE, PPK ;

WILLEY, GR ;

DREW, MGB .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (14) :1100-1102

[2]

FEIRING AE, 1979, J FLUORINE CHEM, V13, P7

[3] AN OVERVIEW OF THE COMMERCIAL DEVELOPMENT OF CHLOROFLUOROCARBON (CFC) ALTERNATIVES [J].

MANZER, LE .

CATALYSIS TODAY, 1992, 13 (01) :13-22

[4]

NAPPA M, 1991, Patent No. 9103661

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