ENANTIOSELECTIVE [2,3]WITTIG REARRANGEMENT INVOLVING A CHIRAL BORON ENOLATE TERMINUS

被引：25

作者：

FUJIMOTO, K ^{[1
]}

NAKAI, T ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT CHEM TECHNOL,MEGURO KU,TOKYO 152,JAPAN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 28期

关键词：

D O I：

10.1016/S0040-4039(00)73309-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first enantioselective version of the ester enolate [2,3]Wittig rearrangement is described which involves a chiral boron enolate with a chiral bis-sulfonamide ligand to provide a high enantioselectivity(>95%ee), along with a high threo diastereoselectivity.

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页码：5019 / 5022

页数：4

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