EXCESS THERMODYNAMIC FUNCTIONS OF CYCLOPENTANE-CARBON TETRACHLORIDE MIXTURES

被引：25

作者：

BOUBLIK, T

LAM, VT

MURAKAMI, S

BENSON, GC

机构：

[1] Division of Pure Chemistry, National Research Council of Canada, Ottawa, Ont.

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 07期

关键词：

D O I：

10.1021/j100727a043

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The thermodynamic behavior of the system cyclopentane-carbon tetrachloride at 25° was investigated by measuring volumes and heats of mixing and by determining the vapor-liquid equilibria. Experimental data for the excess functions were represented by equations of the Redlich-Kister type with coefficients determined by a least-squares method. Interpretation of the results in terms of the theories of Prigogine and of Flory was investigated. Neither theory provides satisfactory estimates of the excess volume.

引用

页码：2356 / &

共 26 条

[1] THERMODYNAMIC PROPERTIES OF MIXTURES OF SMALL NONPOLAR MOLECULES
ABE, A
FLORY, PJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (09) : 1838 - &
[2] HEATS OF MIXING
ADCOCK, DS
MCGLASHAN, ML
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1954, 226 (1165) : 266 - 282
[3] BARKER JA, 1953, DISCUSS FARADAY SOC, P142
[4] BELLEMANS A, 1957, B SOC CHIM BELG, V66, P636
[5] EXCESS PROPERTIES OF SOME AROMATIC-ALICYCLIC SYSTEMS .3. ANALYSIS OF HE AND VE DATA IN TERMS OF THEORY OF FLORY
BENSON, GC
SINGH, J
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (04) : 1345 - &
[6] MOLAR EXCESS GIBBS FREE ENERGIES OF BENZENE-M-XYLENE MIXTURES
BOUBLIK, T
BENSON, GC
[J]. CANADIAN JOURNAL OF CHEMISTRY, 1969, 47 (04): : 539 - &
[7] ENGLERTCHWOLES A, 1955, THESIS U LIBRE
[8] STATISTICAL THERMODYNAMICS OF LIQUID MIXTURES
FLORY, PJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (09) : 1833 - +
[9] 2ND VIRIAL COEFFICIENTS OF VAPOUR MIXTURES
FRANCIS, PG
MCGLASHAN, ML
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1955, 51 (05): : 593 - 599
[10] THERMODYNAMIC PROPERTIES OF THE BENZENE AND CYCLOPENTANE SYSTEM
HERMSEN, RW
PRAUSNITZ, JM
[J]. CHEMICAL ENGINEERING SCIENCE, 1963, 18 (08) : 485 - 494

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