ELASTIC AND INELASTIC NEUTRON STUDIES OF HYDROGEN MOLYBDENUM BRONZES

被引：140

作者：

DICKENS, PG ^{[1
]}

BIRTILL, JJ ^{[1
]}

WRIGHT, CJ ^{[1
]}

机构：

[1] AERE,HARWELL OX11 0RA,OXFORDSHIRE,ENGLAND

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1979年 / 28卷 / 02期

关键词：

D O I：

10.1016/0022-4596(79)90071-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrogen molybdenum bronzes HxMoO3 (∼0.3 < x < 2.0) have been investigated with elastic and inelastic neutron scattering. Neutron diffraction studies of orthorhombic D0.36MoO3 show that deuterium is incorporated as -OD without any major structural change to the MoO3 layer lattice. The inelastic neutron scattering spectra of HxMoO3 phases confirm that, for H0.34MoO3, H is present as -OH, but, for the monoclinic phases H0.93MoO3, H1.68MoO3 and H2.0MoO3, only peaks associated with -OH2 groups are found. © 1979.

引用

页码：185 / 193

页数：9

共 19 条

[1] COHERENT NEUTRON-SCATTERING AMPLITUDES
BACON, GE
[J]. ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1972, A-28 (JUL1) : 357 - &
[2] PHASE RELATIONSHIPS IN SYSTEM HXMOO3 (0 LESS-THAN-OR-EQUAL-TO X LESS-THAN-OR-EQUAL-TO 2.0)
BIRTILL, JJ
DICKENS, PG
[J]. MATERIALS RESEARCH BULLETIN, 1978, 13 (04) : 311 - 316
[3] PROFILE ANALYSIS OF POWDER NEUTRON-DIFFRACTION DATA - ITS SCOPE, LIMITATIONS, AND APPLICATIONS IN SOLID-STATE CHEMISTRY
CHEETHAM, AK
TAYLOR, JC
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1977, 21 (03) : 253 - 275
[4] COLLINS MF, 1969, DISC FARAD SOC, V48, P163
[5] DICKENS PG, 1975, INT REV SCI INORGA 2, V10, P211
[6] UBER MOLYBDANBLAU
GLEMSER, O
LUTZ, G
[J]. ZEITSCHRIFT FUR ANORGANISCHE CHEMIE, 1951, 264 (01): : 17 - 33
[7] GUNTER JR, 1971, J SOLID STATE CHEM, V5, P354
[8] HOWARD J, 1977, C INEL NEUTRON SCATT, V2, P499
[9] KIHLBORG L, 1963, ARK KEMI, V21, P357
[10] ON MOLYBDENUM OXIDE HYDROXIDES GENOTYPIC WITH MOO3
KIHLBORG, L
HAGERSTR.G
RONNQUIST, A
[J]. ACTA CHEMICA SCANDINAVICA, 1961, 15 (05): : 1187 - &

← 1 2 →