THE ORIGIN OF ENANTIOSELECTIVITY IN THE DIHYDROXYLATION OF OLEFINS BY OSMIUM-TETROXIDE AND CINCHONA ALKALOID DERIVATIVES

被引：42

作者：

COREY, EJ

LOTTO, GI

机构：

[1] Department of Chemistry, Harvard University, Cambridge

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 19期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(00)94667-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A logical and simple mechanistic explanation is proposed for the enantioselectivity which has been demonstrated for the catalytic dihydroxylation of certain olefins by osmium tetroxide under the influence of derivatives of quinine and quinidine. © 1990.

引用

页码：2665 / 2668

页数：4

共 21 条

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