ROOM-TEMPERATURE RATE COEFFICIENT FOR THE REACTION BETWEEN CH3O2 AND NO3

被引：21

作者：

CROWLEY, JN

BURROWS, JP

MOORTGAT, GK

POULET, G

LEBRAS, G

机构：

[1] Max-Planck-Institut Für Chemie, Air Chemistry Division, Mainz, D-6500

来源：

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1990年 / 22卷 / 07期

关键词：

D O I：

10.1002/kin.550220703

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The molecular modulation spectroscopic technique was employed to study the kinetics of NO3 radicals produced in the 253.7 nm photolysis of flowing gas mixtures of HNO3/CH4/O2 at room temperature. By computer fitting of the NO3 temporal behavior, a rate coefficient of (2.3 ± 0.7) × 10−12 cm3 molecule−1 s−1 was obtained for the reaction between NO3 and CH3O2 at 298 K. Copyright © 1990 John Wiley & Sons, Inc.

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页码：673 / 681

页数：9

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