THE PREPARATION AND STRUCTURE OF [VL2(SALEN)].CH2CL2 [SALEN = N,N'-ETHYLENEBIS(SALICYLIDENEIMINATE)(2-)] AND OF SOME HOMOLOGS OF RELATED SCHIFF-BASES

被引：31

作者：

HUGHES, DL

KLEINKES, U

LEIGH, GJ

MAIWALD, M

SANDERS, JR

SUDBRAKE, C

WEISNER, J

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 20期

关键词：

D O I：

10.1039/dt9930003093

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The elusive [VI2(salen)] [salen = N,N'-ethylenebis(salicylideneiminate)(2-)] and some of its homologues have been successfully prepared. The structure of [VI2(salen)].CH2Cl2 has been determined by X-ray crystallography, and the conformation is trans-octahedral, as expected, with long V-I separations. The complex is air-stable in the solid state, but appears to be moisture-sensitive in solution, and undergoes autoredox reactions (V(IV) --> V(III), I- --> I2) in ionising solvents.

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页码：3093 / 3096

页数：4

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