THERMAL ANALYSES OF COORDINATION-COMPOUNDS .2. THERMAL-DECOMPOSITION OF PALLADIUM COMPLEXES WITH TRIPHENYLPHOSPHINE, TRIPHENYLARSINE AND TRIPHENYLSTIBINE

被引：6

作者：

BARBIERI, RS ^{[1
]}

BELATTO, CR ^{[1
]}

MASSABNI, AC ^{[1
]}

机构：

[1] UNIV ESTADUAL PAULISTA,INST QUIM,BR-14800900 ARARAQUARA,SP,BRAZIL

来源：

JOURNAL OF THERMAL ANALYSIS | 1995年 / 44卷 / 04期

关键词：

PALLADIUM COMPLEXES; THERMAL ANALYSIS;

D O I：

10.1007/BF02547274

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The compounds [PdCl(2)L(2)] and [PdL(4)] (L=PPh(3), AsPh(3), SbPh(3)) were studied by thermogravimetric and differential thermal analyses in air. The residues of thermal decomposition consist of metallic palladium, except in the case of the complexes containing SbPh(3), when the residues are palladium and antimony mixtures in appropriate proportions with respect to the stoichiometry of the related complexes.

引用

页码：903 / 909

页数：7

共 18 条

[1] UNUSUAL BEHAVIOR OF TRIPHENYLSTIBINE COMPLEXES OF ZEROVALENT PLATINUM [J].

BARBIERI, RS ;

KLEIN, SI ;

MASSABNI, AC .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (21) :1617-1618

[2]

BARBIERI RS, 1989, SEMINARIO BRASILEIRO, V5, P240

[3]

Barbieri RS, 1991, QUIM NOVA, V14, P212

[4] PALLADIUM AND PLATINUM [J].

CHALONER, PA .

COORDINATION CHEMISTRY REVIEWS, 1986, 72 :1-195

[5] NICKEL, PALLADIUM AND PLATINUM, ANNUAL SURVEY COVERING THE YEAR 1981 [J].

CHALONER, PA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 337 (1-3) :431-661

[6] CHEMISTRY OF PLATINUM HYDRIDES .22. FORMATION OF TRINUCLEAR CLUSTER COMPLEXES FROM PLATINUM(II) DIHYDRIDES CONTAINING BULKY PHOSPHINES [J].

CLARK, HC ;

GOEL, AB ;

WONG, CS .

INORGANICA CHIMICA ACTA, 1979, 34 (02) :159-160

[7]

HARTLEY FR, 1970, ORGANOMET CHEM REV A, V6, P119

[8]

HAYWARD PJ, 1969, J CHEM SOC CHEM COMM, P987

[9]

ICHINOSC Y, 1987, B CHEM SOC JPN, V60, P3460

[10]

JENSEN KA, 1875, ACTA CHEM SCAND, V17, P1973

← 1 2 →