A MASS-SPECTRAL STUDY OF EXO- AND ENDO-2-NORBORNYL BROMIDE AND EXO- AND ENDO-8-BROMOBICYCLO[3.2.1]OCTANE BY PHOTOIONIZATION

被引：18

作者：

DEJONGH, DC

SHRADER, SR

ISAKSON, RG

LEBEL, NA

BEYNON, JH

机构：

[1] Department of Chemistry, Wayne State University, Detroit, Michigan

[2] Imperial Chemical Industries Limited, Manchester, Blackley

[3] Department of Chemistry, Purdue University, Lafayette, Indiana

来源：

ORGANIC MASS SPECTROMETRY | 1969年 / 2卷 / 09期

关键词：

D O I：

10.1002/oms.1210020908

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The photoionization, as well as the electron‐impact, mass spectra of exo‐and endo‐norbornyl bromide and of exo‐and endo‐8‐bromobicyclo[3.2.1]octane show that exo‐Br loss is more facile than endo‐Br loss in formation of C7H11⊕ and C8H13⊕, respectively. The relative intensity values are compared with solvolysis data from the same systems. Copyright © 1969 John Wiley & Sons, Ltd.

引用

页码：919 / &

共 15 条

[1]

BEYNON JH, 1967, J SCI INSTR, V44, P293

[2]

BUDZIKIEWICZ H, 1967, MASS SPECTROMETRY OR, P440

[3] MASS SPECTRA OF SOME METHYL NORBORNYL CHLORIDES [J].