STRUCTURE AND SPECTROSCOPIC PROPERTIES OF [(2,6-PH2C6H3O)2TI(MU-CL)2TI(OC6H3PH2-2,6)2] - EVIDENCE FOR A STRONG METAL METAL INTERACTION

被引：24

作者：

HILL, JE ^{[1
]}

NASH, JM ^{[1
]}

FANWICK, PE ^{[1
]}

ROTHWELL, IP ^{[1
]}

机构：

[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

来源：

POLYHEDRON | 1990年 / 9卷 / 13期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0277-5387(00)86582-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compound [(2,6-Ph2C6H3O)2Ti(μ-Cl)2Ti(OC6H3Ph2-2,6)2] which is formed by sodium amalgam reduction of Ti(OC6H3Ph2-2,6)2Cl2 (OC6H3Ph2-2,6 = 2,6-diphenylphenoxide) contains a relatively short TiTi distance of 2.9827(7) Å and acute Ti(μ-Cl)Ti angles of 77.79(3) and 78.05(3)°. Crystal data at -130°C: space group P1; a = 13.342(4), b = 13.808(4), c = 16.057(3) Å, α = 97.35(2), β = 104.63(2), γ = 91.64(2)°, Z = 2; ρ{variant}calc = 1.346 g cm-3. © 1990.

引用

收藏

页码：1617 / 1619

页数：3

相关论文

共 28 条

[1] CARBON-HYDROGEN-TRANSITION METAL BONDS [J].

BROOKHART, M ;

GREEN, MLH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 250 (01) :395-408

[2] THE CHEMISTRY OF STERICALLY CROWDED ARYLOXIDE LIGANDS .7. SYNTHESIS, STRUCTURE AND SPECTROSCOPIC PROPERTIES OF SOME GROUP-4 AND GROUP-5 METAL DERIVATIVES OF 2,6-DIPHENYLPHENOXIDE [J].

CHESNUT, RW ;

DURFEE, LD ;

FANWICK, PE ;

ROTHWELL, IP ;

FOLTING, K ;

HUFFMAN, JC .

POLYHEDRON, 1987, 6 (11) :2019-2026

[3] SYNTHESIS, STRUCTURE, AND BONDING OF MONONUCLEAR ARYLOXIDE DERIVATIVES OF NIOBIUM IN OXIDATION-STATES +5, +3, +2, AND +1 [J].

COFFINDAFFER, TW ;

STEFFY, BD ;

ROTHWELL, IP ;

FOLTING, K ;

HUFFMAN, JC ;

STREIB, WE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (13) :4742-4749

[4]

Cotton F.A, 1982, MULTIPLE BONDS METAL

[5] THE STRUCTURES OF METAL METAL-BONDED EDGE-SHARING BIOCTAHEDRAL COMPLEXES [J].

COTTON, FA .

POLYHEDRON, 1987, 6 (04) :667-677

[6] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF 3 COMPOUNDS WITH ZR(III)-ZR(III) BONDS - ZR2CL6(DPPE)2.2C2H4CL2.1.5C6H5CH3,ZR2CL6(PME2PH)4, AND ZR2CL6(PET3)4 [J].

COTTON, FA ;

DIEBOLD, MP ;

KIBALA, PA .

INORGANIC CHEMISTRY, 1988, 27 (05) :799-804

[7] SOLID-STATE STRUCTURES OF DINITROSYLIRON IODIDE AND DINITROSYLCOBALT IODIDE - STEREOCHEMICAL CONSEQUENCES OF STRONG METAL-METAL INTERACTIONS IN LIGAND-BRIDGED COMPLEXES [J].

DAHL, LF ;

DEGIL, ER ;

FELTHAM, RD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (07) :1653-&

[8] MONO-ETA-CYCLOHEPTATRIENYLTITANIUM CHEMISTRY - SYNTHESIS, MOLECULAR AND ELECTRONIC-STRUCTURES, AND REACTIVITY OF THE COMPLEXES [TI(ETA-C7H7)L2X] (L = TERTIARY PHOSPHINE, O-DONOR OR N-DONOR LIGAND - X = CL OR ALKYL) [J].

DAVIES, CE ;

GARDINER, IM ;

GREEN, JC ;

GREEN, MLH ;

HAZEL, NJ ;

GREBENIK, PD ;

MTETWA, VSB ;

PROUT, K .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (04) :669-683

[9] A BIS(TRIMETHYLSTANNYL)AMIDO COMPLEX OF TITANIUM - THE SYNTHESIS AND STRUCTURES OF [TICL2(OC6H3PH2-2,6)2] AND [TICL(N(SNME3)2)(OC6H3PH2-2,6)2] [J].

DILWORTH, JR ;

HANICH, J ;

KRESTEL, M ;

BECK, J ;

STRAHLE, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 315 (01) :C9-C12

[10] SYNTHESIS AND STRUCTURE OF [NATI(2,6-ME2C6H3O)4(PY)]2 - A DIMERIC MATERIAL CONTAINING A NOVEL PHENOXIDE BRIDGE [J].

DURFEE, LD ;

FANWICK, PE ;

ROTHWELL, IP .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1988, 27 (09) :1181-1182