TETRAGONAL DISTORTION FROM CUBIC SYMMETRY AT LOWER TEMPERATURES IN THE CS2NALNCL6 COMPOUNDS (ELPASOLITES) WITH LIGHT LANTHANIDES

被引:28
作者
NEVALD, R [1 ]
VOSS, FW [1 ]
NIELSEN, OV [1 ]
AMBERGER, HD [1 ]
FISCHER, RD [1 ]
机构
[1] UNIV HAMBURG,INST ANORGAN & ANGEW CHEM,D-2000 HAMBURG 13,FED REP GER
关键词
D O I
10.1016/0038-1098(79)90871-8
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Single crystal magnetization- and NMR-measurements show that the Cs2NaLnCl6 compounds with the light rare earth Ce and Nd, contrary to that with the heavy rare earth Ho, are tetragonally distorted from cubic symmetry at lower temperatures. Because of this distortion, detailed single crystal magnetization data are required in order to evaluate the Ln crystal-field level scheme. The size of the distortion is such that it splits the ground quadruplet of Nd+3 into doublets nearly two Kelvin apart. © 1979.
引用
收藏
页码:1223 / 1225
页数:3
相关论文
共 10 条
[1]   ELECTRONIC-STRUCTURE OF HIGHLY SYMMETRICAL COMPOUNDS OF LANTHANIDES AND ACTINIDES .10. CRYSTAL-FIELD SPLITTING PATTERN OF CS2NAPR(III)CL6 IN LOW ENERGETIC REGION [J].
AMBERGER, HD .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1978, 439 (02) :48-56
[2]   ELECTRONIC-STRUCTURE OF HIGHLY-SYMMETRICAL COMPOUNDS OF LANTHANIDES AND ACTINIDES .7. ELECTRONIC RAMAN-SPECTRA OF LANTHANIDE ELPASOLITES OF TYPE CS2NALN(3)CL6 [J].
AMBERGER, HD ;
ROSENBAUER, GG ;
FISCHER, RD .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1977, 38 (04) :379-385
[3]   ELECTRON-STRUCTURE OF HIGHLY SYMMETRIC LANTHANOID AND ACTINOID COMPOUNDS .6. ELECTRONIC RAMAN-SPECTRUM OF CS2NACE(III)CL6 [J].
AMBERGER, HD ;
ROSENBAUER, GG ;
FISCHER, RD .
MOLECULAR PHYSICS, 1976, 32 (05) :1291-1298
[4]  
ANISTRATOV AJ, 1978, SOV PHYS-SOLID STATE, V20, P2138
[5]   SPECTROSCOPIC ANALYSIS OF LITHIUM TERBIUM TETRAFLUORIDE [J].
CHRISTENSEN, HP .
PHYSICAL REVIEW B, 1978, 17 (10) :4060-4068
[6]   CRYSTAL-FIELD ANALYSIS FOR SUSCEPTIBILITY OF LANTHANIDE COMPOUNDS OF FORM CS2NARCL6 [J].
DUNLAP, BD ;
SHENOY, GK .
PHYSICAL REVIEW B, 1975, 12 (07) :2716-2724
[7]   MAGNETIC-SUSCEPTIBILITIES OF TRIVALENT LANTHANIDE IONS IN AN OCTAHEDRAL ENVIRONMENT [J].
HOEHN, MV ;
KARRAKER, DG .
JOURNAL OF CHEMICAL PHYSICS, 1974, 60 (02) :393-397
[8]   MAGNETIC SUSCEPTIBILITY OF YB3+ IN AN OCTAHEDRAL ENVIRONMENT [J].
KARRAKER, DG .
JOURNAL OF CHEMICAL PHYSICS, 1971, 55 (03) :1084-&
[9]   TEMPERATURE AND FIELD INDEPENDENCE OF THE FLUORINE AND LITHIUM NMR SHIFT TENSORS IN LITHIUM RARE-EARTH TETRAFLUORIDES [J].
NEVALD, R ;
HANSEN, PE .
PHYSICAL REVIEW B, 1978, 18 (09) :4626-4634
[10]   LOW-TEMPERATURE CRYSTALLINE PHASE-TRANSITION IN SOME ELPASOLITE-HEXACHLORIDES [J].
SCHWARTZ, RW ;
WATKINS, SF ;
OCONNOR, CJ ;
CARLIN, RL .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1976, 72 :565-570