STRUCTURE OF DIMETHYL(PHENYL)PHOSPHONIUM TRIS(1,2-BENZENEDITHIOLATO)TUNGSTEN(V)

被引：29

作者：

BURROW, TE ^{[1
]}

MORRIS, RH ^{[1
]}

HILLS, A ^{[1
]}

HUGHES, DL ^{[1
]}

RICHARDS, RL ^{[1
]}

机构：

[1] UNIV SUSSEX,AFRC,IPSR,NITROGEN FIXAT LAB,BRIGHTON BN1 9RQ,E SUSSEX,ENGLAND

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270193001295

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of [WCl4(PMe2Ph)3] with C6H4(SH)2-1,2 in toluene gives dark brown [W(C6H4S2-1,2)2(PMe2Ph)2], which on standing in solution gives deep green [PHMe2Ph][W(C6H4S2-1,2)3]. The X-ray structure of [PHMe2Ph][W(C6H4S2-1,2)3] shows the tungsten to be coordinated by three (C6H4S2-1,2)2- ligands with an average W-S distance of 2.386 (6) angstrom in a geometry which is halfway between octahedral and trigonal prismatic.

引用

页码：1591 / 1594

页数：4

共 14 条

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