TEMPERATURE AND PRESSURE DERIVATIVES OF THE ELASTIC-CONSTANTS OF CUBIC RUBIDIUM CYANIDE

The temperature and pressure derivatives of all elastic constants of rubidium cyanide have been measured from 133 to 380 K respectively from 0 to 1500 × 105 Nm-2 by ultrasonic methods. The thermoelastic behaviour resembles that of KCN and NaCN. A strong softening of the shear resistance c44 approaching the transition temperature from higher temperatures is observed. The pressure derivatives are also quite similar to those of KCN and NaCN, but fully different from those of normal alkali halides of rocksalt-type. This behaviour confirms a rule already observed in other isotypic crystal groups: the quasi-invariant pressure derivatives are shifted in a characteristic way for a certain structure type, if rare-gas-like ions are replaced by asymmetric ions. The nonlinear elastic behaviour is qualitatively interpreted by interactions of volume-conserving type as existing in fluids. © 1979.