THE PALLADIUM-CATALYZED REACTIONS OF 2-ALKYNYL CARBONATES WITH TERMINAL ACETYLENES - A NEW SYNTHETIC METHOD FOR 1,2-DIEN-4-YNES

被引：26

作者：

MANDAI, T ^{[1
]}

MURAYAMA, H ^{[1
]}

NAKATA, T ^{[1
]}

YAMAOKI, H ^{[1
]}

OGAWA, M ^{[1
]}

KAWADA, M ^{[1
]}

TSUJI, J ^{[1
]}

机构：

[1] OKAYAMA UNIV SCI,DEPT APPL CHEM,RIDAI CHO,OKAYAMA 700,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 417卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(91)80180-R

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of substituted 2-alkynyl carbonates with terminal acetylenes in the presence of palladium-phosphine complex and copper iodide as catalysts proceeds in THF to give 1,2-dien-4-ynes (allenyl acetylenes) in good yields. The reaction proceeds by the formation of allenylpalladium complex as an intermediate.

引用

页码：305 / 311

页数：7

共 20 条

[1] NATURAL ACETYLENES .19. METABOLITES FROM SOME PORIA SPECIES
BEW, RE
CAMBIE, RC
JONES, ERH
LOWE, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1966, (02): : 135 - +
[2] NATURAL ACETYLENES .18. SOME ALLENIC POLYACETYLENES FROM BASIDOMYCETES
BEW, RE
CHAPMAN, JR
JONES, ERH
LOWE, BE
LOWE, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1966, (02): : 129 - &
[3] MYCOMYCIN .3. THE STRUCTURE OF MYCOMYCIN, AN ANTIBIOTIC CONTAINING ALLENE, DIACETYLENE AND CIS, TRANS-DIENE GROUPINGS
CELMER, WD
SOLOMONS, IA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (06) : 1372 - 1376
[4] Heck R. F., 1985, PALLADIUM REAGENTS O
[5] HIGHLY STEREOSPECIFIC PALLADIUM-CATALYZED VINYLATION OF VINYLIC HALIDES UNDER SOLID-LIQUID PHASE-TRANSFER CONDITIONS
JEFFERY, T
[J]. TETRAHEDRON LETTERS, 1985, 26 (22) : 2667 - 2670
[6] JEFFERYLUONG T, 1983, SYNTHESIS-STUTTGART, P32
[7] PALLADIUM-CATALYZED SYNTHESIS OF ALLENES
JEFFERYLUONG, T
LINSTRUMELLE, G
[J]. TETRAHEDRON LETTERS, 1980, 21 (52) : 5019 - 5020
[8] PALLADIUM-CATALYZED PROPARGYLIC VS ALLYLIC ALKYLATION
KEINAN, E
BOSCH, E
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (21) : 4006 - 4016
[9] KLEIJN H, 1982, RECL TRAV CHIM PAY B, V101, P97
[10] PALLADIUM-CATALYZED REACTIONS OF 2-ALKYNYL CARBONATES WITH TERMINAL ACETYLENES - A NEW SYNTHETIC METHOD FOR 1,2-DIEN-4-YNES
MANDAI, T
NAKATA, T
MURAYAMA, H
YAMAOKI, H
OGAWA, M
KAWADA, M
TSUJI, J
[J]. TETRAHEDRON LETTERS, 1990, 31 (49) : 7179 - 7180

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