SOL-GEL SYNTHESIS OF SUPERCONDUCTING YBA2CU4O8 USING ACETATE AND TARTRATE PRECURSORS

被引：48

作者：

KAREIVA, A ^{[1
]}

KARPPINEN, M ^{[1
]}

NIINISTO, L ^{[1
]}

机构：

[1] VILNIUS UNIV,DEPT GEN & INORGAN CHEM,VILNIUS,LITHUANIA

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1994年 / 4卷 / 08期

关键词：

D O I：

10.1039/jm9940401267

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A simple sol-gel route starting from an aqueous mixture of Y, Ba and Cu acetates and tartrates has been refined to prepare superconducting YBa2Cu4O8 at an oxygen pressure of 1 atm. Thermal decomposition of the fabricated gels was studied by means of thermogravimetry. In order to interpret the decomposition mechanisms, both individual and double gels of Y, Ba and Cu were studied. The synthesis products were characterized by X-ray diffraction for phase purity, by thermal analysis for oxygen stability and by SQUID measurements for superconducting properties.

引用

页码：1267 / 1270

页数：4

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