REACTIVE CRYSTALLIZATION OF CALCIUM-CARBONATE BY GAS-LIQUID AND LIQUID LIQUID REACTIONS

被引：18

作者：

KOTAKI, Y ^{[1
]}

TSUGE, H ^{[1
]}

机构：

[1] KEIO UNIV,DEPT APPL CHEM,3-14-1 HIYOSHI,KOHOKU KU,YOKOHAMA,KANAGAWA 223,JAPAN

来源：

CANADIAN JOURNAL OF CHEMICAL ENGINEERING | 1990年 / 68卷 / 03期

关键词：

agglomeration of CaCO[!sub]3[!/sub; calcium carbonate crystallization; crystallization kinetics; reactive crystallization;

D O I：

10.1002/cjce.5450680313

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Crystallization of calcium carbonate by gas‐liquid and liquid‐liquid reactions in a continuous MSMPR crystallizer was conducted over a wide range of suspension densities. The effects of operating factors and reaction mechanism on the cyrstallization kinetics were investigated. The crystallization kinetics for both reaction systems are correlated by the power law model and these correlations depend on the suspension density regions. The kinetic orders in the power law model are correlated with carbonate alkalinity irrespective of the reaction mechanism and the suspension density. Copyright © 1990 Canadian Society for Chemical Engineering

引用

页码：435 / 442

页数：8

共 8 条

[1] [Anonymous], 1978, CHEM ENV ENG
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[3] PETERS RW, 1981, AM I CHEM ENG S SERI, V77, P49
[4] SCHIERHOLZ PM, 1975, AICHE S 151, V71, P248
[5] SHIROTSUKA T, 1966, KAGAKU KOGAKU, V30, P833
[6] CALCIUM-CARBONATE CRYSTALLIZATION KINETICS
SWINNEY, LD
STEVENS, JD
PETERS, RW
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1982, 21 (01): : 31 - 36
[7] TOYOKURA K, 1977, KAGAKU KOGAKU RONBUN, V3, P48
[8] REACTIVE CRYSTALLIZATION OF CALCIUM-CARBONATE BY LIQUID-LIQUID REACTION
TSUGE, H
KOTAKI, Y
HIBINO, S
[J]. JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1987, 20 (04) : 374 - 379

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