NOVEL DIRECT HYDROGENATION PROCESS OF AROMATIC CARBOXYLIC-ACIDS TO THE CORRESPONDING ALDEHYDES WITH ZIRCONIA CATALYST

被引：126

作者：

YOKOYAMA, T ^{[1
]}

SETOYAMA, T ^{[1
]}

FUJITA, N ^{[1
]}

NAKAJIMA, M ^{[1
]}

MAKI, T ^{[1
]}

FUJII, K ^{[1
]}

机构：

[1] MITSUBISHI KASEI CORP,KUROSAKI PLANT,YAHATANISHI KU,KITAKYUSHU 806,JAPAN

来源：

APPLIED CATALYSIS A-GENERAL | 1992年 / 88卷 / 02期

关键词：

AROMATIC ALDEHYDE; CARBOXYLIC ACID; HYDROGENATION; ZIRCONA;

D O I：

10.1016/0926-860X(92)80212-U

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel process for synthesizing aromatic aldehydes by a direct hydrogenation reaction of the corresponding carboxylic acids was established. The catalyst, modified zirconia, showed satisfactory performance for commercial production. The optimization of the catalyst, application to various carboxylic acids, and mechanistic considerations using reaction kinetics and FT-IR spectroscopy are reported.

引用

页码：149 / 161

页数：13

共 12 条

[1] CARBERRY JJ, 1976, CHEM CATALYTIC REACT, P387
[2] Catalytic reduction by formic acid under pressure - Part I The preparation of aldehydes from carboxylic acids with titanium dioxide as catalyst
Davies, RR
Hodgson, HH
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1943, : 84 - 86
[3] Feinstein A., 1976, US Pat, Patent No. [3935265, 3, 935, 265]
[4] FERRERO RM, 1986, Patent No. 4613700
[5] NOVEL CATALYTIC PROPERTY OF MAGNESIUM-OXIDE FOR HYDROGENATION OF 1,3-BUTADIENE
HATTORI, H
TANAKA, Y
TANABE, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (15) : 4652 - 4653
[6] MAKI T, 1985, Patent No. 126242
[7] HYDROGENATION OF CONJUGATED DIENES OVER ZRO2 BY H-2 AND CYCLOHEXADIENE
NAKANO, Y
YAMAGUCHI, T
TANABE, K
[J]. JOURNAL OF CATALYSIS, 1983, 80 (02) : 307 - 314
[8] CATALYSIS BY SOLID SUPERACIDS .18. NAFION-H PERFLUORINATED RESIN SULFONIC-ACID PROMOTED DEACETYLATION AND DECARBOXYLATION OF AROMATICS
OLAH, GA
LAALI, K
MEHROTRA, AK
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (19) : 3360 - 3362
[9] IR-SPECTRA OF HYDROGEN ADSORBED ON ZRO2
ONISHI, T
ABE, H
MARUYA, KI
DOMEN, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (09) : 617 - 618
[10] Strojny E.J., 1982, US Pat, Patent No. 4328373

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