A PHYSICOCHEMICAL STUDY OF REVERSE TRANSPORT-SYSTEM BASED ON NONEQUILIBRIUM THERMODYNAMICS

被引：5

作者：

YANG, WK

YAMAUCHI, A

KIMIZUKA, H

机构：

[1] KYUSHU UNIV 33,FAC SCI,DEPT CHEM,HIGASHI KU,FUKUOKA 812,JAPAN

[2] DONG GUK UNIV,COLL NAT SCI,DEPT CHEM,KYONGYU 780714,SOUTH KOREA

来源：

JOURNAL OF MEMBRANE SCIENCE | 1992年 / 70卷 / 2-3期

关键词：

COUPLED FACILITATED TRANSPORT; LIQUID MEMBRANES; MEMBRANE POTENTIALS; THERMODYNAMICS;

D O I：

10.1016/0376-7388(92)80113-X

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Reverse transport in a liquid membrane system was studied on the basis of nonequilibrium thermodynamics. The electrochemical affinities which drive the ion flux in the system accompanying the chemical reaction were described in the form of the dissipation function. The system was confirmed to be a typical physicochemical system. In addition, using the equations developed in this study, several membrane parameters were estimated and the correlation between the diffusional ion conductance and ion concentration within the liquid membrane was discussed.

引用

页码：277 / 282

页数：6

共 19 条

[1]

[Anonymous], 1965, NONEQUILIBRIUM THERM

[2] SELECTIVE MEMBRANE FOR TRANSPORTING SODIUM ION AGAINST ITS CONCENTRATION GRADIENT [J].