CORRELATION-ANALYSIS IN ORGANIC-CHEMISTRY (CAOC) - THE CROSS-ROAD

被引：1

作者：

ABBOUD, JLM

NOTARIO, R

机构：

来源：

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE | 1992年 / 89卷 / 7-8期

关键词：

D O I：

10.1051/jcp/1992891531

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Intrinsic gas-phase proton basicities (GB) of organic compounds are used to generate linear free-energy relationships (LFER). Examples are given of correlations of GBs with thermodynamic and kinetic data obtained both in the gas-phase and in solution. It is shown that under conditions of minimal differential solvation effects, systems can be found in solution that reproduce the gas-phase pattern of structural effects on reactivity. In line with the dynamic character of CAOC, these LFER shed light on several problems while raising a number of important questions.

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页码：1531 / 1543

页数：13

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