INTERMOLECULAR HYDROGEN-BONDING AS AN AID TO THE PREFERENTIAL EXHIBITION OF THE SMECTIC C-PHASE IN TROPONOID LIQUID-CRYSTALS

被引：25

作者：

MORI, A

TAKESHITA, H

NIMURA, R

ISOBE, M

机构：

[1] KYUSHU UNIV,KASUGA,FUKUOKA 816,JAPAN

[2] KYUSHU UNIV,GRAD SCH ENGN SCI 39,KASUGA,FUKUOKA 816,JAPAN

来源：

LIQUID CRYSTALS | 1993年 / 14卷 / 03期

关键词：

D O I：

10.1080/02678299308027758

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2-(4-Alkoxybenzoyloxy)-5-alkylaminotropone and 5-alkoxy-244-alkylaminobenzoyloxy)tropone liquid crystals showed the smectic C phase exclusively. Variable temperature FT-IR spectra indicated that intermolecular hydrogen bonding between the NH and tropone C=O groups assisted the appearance of the mesophase. 4-Alkoxyphenyl 4-alkylaminobenzoates were non-mesogenic.

引用

页码：821 / 827

页数：7

共 14 条

[1] GRAY GW, 1953, J CHEM SOC, P4179
[2] Gray GW, 1962, MOL STRUCTURE PROPER, P162
[3] CARBOHYDRATE LIQUID-CRYSTALS
JEFFREY, GA
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1986, 19 (06) : 168 - 173
[4] NEW APPROACH TO MESOPHASE STABILIZATION THROUGH HYDROGEN-BONDING MOLECULAR-INTERACTIONS IN BINARY-MIXTURES
KATO, T
FRECHET, JMJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (22) : 8533 - 8534
[5] SELF-ASSEMBLY OF A TWIN LIQUID-CRYSTALLINE COMPLEX THROUGH INTERMOLECULAR HYDROGEN BONDINGS
KATO, T
FUJISHIMA, A
FRECHET, JMJ
[J]. CHEMISTRY LETTERS, 1990, (06) : 919 - 922
[6] HYDROGEN-BONDED LIQUID-CRYSTALS - A NOVEL MESOGEN INCORPORATING NONMESOGENIC 4,4'-BIPYRIDINE THROUGH SELECTIVE RECOGNITION BETWEEN HYDROGEN-BONDING DONOR AND ACCEPTOR
KATO, T
WILSON, PG
FUJISHIMA, A
FRECHET, JMJ
[J]. CHEMISTRY LETTERS, 1990, (11) : 2003 - 2006
[7] THE 1ST SYNTHESIS OF THE ROD-TYPE MONOCYCLIC LIQUID-CRYSTALS WITH 2-ACYLOXYTROPONE STRUCTURE
KIDA, K
MORI, A
TAKESHITA, H
[J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1991, 199 : 387 - 391
[8] CRUCIAL ROLE OF THE TROPONE C=O GROUP IN PREFERENTIAL EXHIBITION OF SMECTIC C-PHASE THROUGH INTERMOLECULAR HYDROGEN-BONDING
MORI, A
NIMURA, R
ISOBE, M
TAKESHITA, H
[J]. CHEMISTRY LETTERS, 1992, (05) : 859 - 862
[9] ASSISTANCE OF THE INTERMOLECULAR HYDROGEN-BONDING ON THE APPEARANCE OF THE SMECTIC C PHASE IN 2-(4-ALKOXYBENZOYLOXY)-5-ALKYLAMINOTROPONE LIQUID-CRYSTALS
MORI, A
NIMURA, R
TAKESHITA, H
[J]. CHEMISTRY LETTERS, 1991, (01) : 77 - 80
[10] PREPARATION OF NEW LIQUID-CRYSTALS WITH A BENZOYLOXYTROPONE CORE
MORI, A
UCHIDA, M
TAKESHITA, H
[J]. CHEMISTRY LETTERS, 1989, (04) : 591 - 592

← 1 2 →