REACTIVITY AND FAR INFRARED SPECTRA OF PT11 AND PD2 COMPLEXES WITH NITROGEN DONOR LIGANDS

被引：24

作者：

BOSCHI, T

DEGANELL.G

CARTURAN, G

机构：

[1] Laboratorio di Chimica e Technologia dei Radioelementi C.N.R., Padova

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 08期

关键词：

D O I：

10.1016/0022-1902(69)80573-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Farr i.r. spectra of the series of complexes cis-[M(py)2X2], [M(en)X2], and [M(bipy)X2] (M = Pt, Pd; X = Cl, Br, I, py = pyridine, en = ethylenediamine, bipy = 1,2-bipyridyl) are reported. The higher reactivity of [Pt(bipy)X2] over the other platinum substrates toward halide displacement by dithioxamide is interpreted as resulting from the stabilization of the transition state rather than from weakening of the MX bond. © 1969.

引用

页码：2423 / &

共 13 条

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