PHOTO-LUMINESCENCE METHODS FOR EVALUATION OF SOLUBILIZATION PARAMETERS AND DYNAMICS OF MICELLAR AGGREGATES - LIMITING CASES WHICH ALLOW ESTIMATION OF PARTITION-COEFFICIENTS, AGGREGATION NUMBERS, ENTRANCE AND EXIT RATES

被引:227
作者
YEKTA, A [1 ]
AIKAWA, M [1 ]
TURRO, NJ [1 ]
机构
[1] COLUMBIA UNIV,DEPT CHEM,NEW YORK,NY 10027
关键词
D O I
10.1016/0009-2614(79)80710-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Poisson statistics is a nature consequence of a distribution of solubilized molecules among micellar aggregates. With postulates of non-cooperativity and thermodynamic considerations, relationships for extent of solute fractionation between the micellar phase and the aqueous phase are derived, as are expressions for the handling of experimental data from the quenching of photoluminescence probes of micellar aggregates. © 1979.
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页码:543 / 548
页数:6
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