SYNTHESIS AND CHARACTERIZATION OF THE HETEROBINUCLEAR MU-METHYLENE COMPLEX (CO)4FEPT(PPH3)2(MU-CH2)

被引：11

作者：

MIRKIN, CA

GEOFFROY, GL

MACKLIN, PD

RHEINGOLD, AL

机构：

[1] PENN STATE UNIV,DEPT CHEM,UNIVERSITY PK,PA 16802

[2] US MIL ACAD,DEPT CHEM,W POINT,NY 10996

[3] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19716

来源：

INORGANICA CHIMICA ACTA | 1990年 / 170卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0020-1693(00)80402-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new bridging methylene complex (CO)4FePt (PPh3)2(μ-CH2), has been prepared by the reaction of Fe2(μ-CH2)(CO)8 with Pt(PPh3)2(CH2CH2) and has been crystallographically characterized: P21/c, a = 10.338(2), b = 19.604(5), c = 18.422(4) Å, β = 105.30(2), Dc = 1.65, Z = 4, R = 3.54, Rw = 3.64 for 4052 reflections with Fo ≥ 5 σ(Fo). The iron atom has a distorted octahedral geometry defined by the four carbonyl ligands, the platinum atom, and the methylene ligand, whereas the platinum center has a distorted square planar geometry. © 1990.

引用

页码：11 / 15

页数：5

共 10 条

[1] (MU-METHYLENE)DIPLATINUM COMPLEXES - THEIR SYNTHESES, STRUCTURES, AND PROPERTIES [J].