ALKOXIDE-PROMOTED DECOMPOSITION OF N-HALO-ALPHA-AMINO ACIDS IN AQUEOUS-MEDIUM

被引：6

作者：

ARMESTO, XL ^{[1
]}

CANLE, M ^{[1
]}

GARCIA, MV ^{[1
]}

LOSADA, M ^{[1
]}

RODRIGUEZ, P ^{[1
]}

SANTABALLA, JA ^{[1
]}

机构：

[1] UNIV A CORUNA, FAC CIENCIAS, DEPT QUIM FUNDAMENTAL & IND, E-15071 LA CORUNA, SPAIN

来源：

TETRAHEDRON | 1994年 / 50卷 / 07期

关键词：

D O I：

10.1016/S0040-4020(01)85084-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

a kinetic study of the alkoxide-promoted decomposition of N-halo derivatives of glycine and sarcosine in aqueous solution has been carried out. The deuterium isotope effect and the leaving group effect, together with an analysis of the data in terms of the cross interaction parameter p(XY) and of the More O'Ferrall-Jencks diagram suggest that the reaction takes place through a concerted non-synchronous mechanism.

引用

页码：2265 / 2276

页数：12

共 19 条

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