HIGH-NUCLEARITY OXOMOLYBDENUM(V) COMPLEXES

被引：78

作者：

CHAE, HK

KLEMPERER, WG

MARQUART, TA

机构：

[1] UNIV ILLINOIS,BECKMAN INST ADV SCI & TECHNOL,URBANA,IL 61801

[2] UNIV ILLINOIS,DEPT CHEM,URBANA,IL 61801

来源：

COORDINATION CHEMISTRY REVIEWS | 1993年 / 128卷 / 1-2期

关键词：

D O I：

10.1016/0010-8545(93)80031-Y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

During the past decade, a new family of high nuclearity oxometalates has emerged, oxomolybdenum(V) complexes whose d-electrons are localized in Mo(v)-Mo(v) bonds. The structure types of all known complexes in this family are reviewed, including nine different (Mo(V)-Mo(V)) monomer, dimer, trimer, tetramer, hexamer, and octadecamer structures, with an emphasis on high-nuclearity structures. In each case, oxomolybdenum(V) core structures are identified and analyzed with regard to degree of polymerization, degree of condensation, and oxygen packing, and an effort is made to identify smaller complexes as subunits of larger structures.

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页码：209 / 224

页数：16

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