DETERMINATION OF THE RELATIVE RATES OF ADDITION OF STYRENE AND ACRYLONITRILE TO THE 1-(1,3-DIPHENYLPROPYL) AND 1-(3-CYANO-1-PHENYLPROPYL) RADICALS - EVIDENCE FOR A PENULTIMATE EFFECT IN RADICAL COPOLYMERIZATION

被引：28

作者：

CYWAR, DA ^{[1
]}

TIRRELL, DA ^{[1
]}

机构：

[1] UNIV MASSACHUSETTS,DEPT POLYMER SCI & ENGN,AMHERST,MA 01003

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1989年 / 111卷 / 19期

关键词：

D O I：

10.1021/ja00201a041

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：7544 / 7553

页数：10

共 18 条

[1] The mechanism of copolymerilzatlon [J].

Alfrey, T ;

Goldfinger, G .

JOURNAL OF CHEMICAL PHYSICS, 1944, 12 (06) :205-209

[2] REACTIVITIES OF MONOMERS TOWARD THE 2-CYANO-2-PROPYL RADICAL BY NMR-STUDY OF END GROUPS IN COPOLYMERS [J].

BEVINGTON, JC ;

HUCKERBY, TN ;

HUTTON, NWE .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1982, 20 (09) :2655-2660

[3] MODEL COPOLYMERIZATION REACTIONS - DETERMINATION OF THE RELATIVE RATES OF ADDITION OF STYRENE AND ACRYLONITRILE TO THE 1-PHENYLETHYL RADICAL [J].

CYWAR, DA ;

TIRRELL, DA .

MACROMOLECULES, 1986, 19 (12) :2908-2911

[4] TECHNIQUES IN THE USE OF CARBON-14 [J].

DAUBEN, WG ;

REID, JC ;

YANKWICH, PE .

ANALYTICAL CHEMISTRY, 1947, 19 (11) :828-832

[5] STUDY OF THE ROLE OF CHARGE-TRANSFER COMPLEXES IN SOME BULK-PHASE FRE-RADICAL POLYMERIZATIONS [J].

FARMER, RG ;

HILL, DJT ;

ODONNELL, JH .

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1980, A14 (01) :51-68

[6] FREE-RADICAL COPOLYMERIZATION .3. DETERMINATION OF RATE CONSTANTS OF PROPAGATION AND TERMINATION FOR THE STYRENE METHYL-METHACRYLATE SYSTEM - A CRITICAL TEST OF TERMINAL-MODEL KINETICS [J].

FUKUDA, T ;

MA, YD ;

INAGAKI, H .

MACROMOLECULES, 1985, 18 (01) :17-26

[7]

Giese B., 1986, RADICAL ORGANIC SYNT

[8]

Gilman H., 1929, J AM CHEM SOC, V51, P1576

[9] ANALYSIS OF THE MECHANISM OF COPOLYMERIZATION OF STYRENE AND ACRYLONITRILE [J].

HILL, DJT ;

ODONNELL, JH ;

OSULLIVAN, PW .

MACROMOLECULES, 1982, 15 (04) :960-966

[10] MODEL COPOLYMERIZATION REACTIONS - DIRECT OBSERVATION OF A PENULTIMATE EFFECT IN A MODEL STYRENE ACRYLONITRILE COPOLYMERIZATION [J].

JONES, SA ;

PREMENTINE, GS ;

TIRRELL, DA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (18) :5275-5276

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