Dehydration of alpha-phenylcyclohexanone oxime

被引：35

作者：

Wenkert, Ernest ^{[1
]}

Barnett, Buford F. ^{[1
]}

机构：

[1] Iowa State Univ, Dept Chem, Ames, IA 50011 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1960年 / 82卷 / 17期

关键词：

D O I：

10.1021/ja01502a055

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The pyrolysis of alpha-phenylcyclohexanone oxime in a closed system and the characterization of the resulting products are described. The oxidation of tetrahydrocarbazole to carbazole by cyclohexanone oxime and the significance of this novel dehydrogenation in relation to the oxime pyrolysis is discussed. Both the thermal and acid-catalyzed conversions of 2-hydroxylarninobiphenyl to azo, azoxy and amino systems are portrayed. A variant of the Neber reaction on an ester of 2-phenylcyclohexan one oxime is described.

引用

页码：4671 / 4675

页数：5

共 9 条

[1]

BELL F, 1928, J CHEM SOC, P2773

[2] THE PROBLEM OF THE UNSATURATED 3-MEMBERED RING CONTAINING NITROGEN [J].