THE MOLECULAR-STRUCTURE OF ME3TICP-STAR IN THE GAS-PHASE

被引：18

作者：

BLOM, R

RYPDAL, K

MENA, M

ROYO, P

SERRANO, R

机构：

[1] UNIV OSLO,DEPT CHEM,BOX 1033,N-0315 OSLO 3,NORWAY

[2] UNIV ALCALA DE HENARES,DEPT QUIM INORGAN,E-28871 ALCALA DE HENARES,SPAIN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 391卷 / 01期

关键词：

D O I：

10.1016/0022-328X(90)80155-S

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The thermal average molecular structure of Me3TiCp{black star} has been determined by gas phase electron diffraction (GED). The GED data are consistent with a molecular model in which the TiMe3 fragment has C3v symmetry and the TiCp{black star} fragment has C5v symmetry. No static tilt of the methyl groups attached to titanium can be detected, although a flattening of the methyl groups with TiCH 103.8(1.2)° is obtained. The TiC(Me) bond distance is 210.7(5) pm, and the TiC(Cp{black star}) distance 238.0(5) pm. © 1990.

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页码：47 / 51

页数：5

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