THE ABSORPTION OF SUPERSONICALLY EXPANDED CS2 IN THE VUV REGION

被引：15

作者：

MUALEM, R

GEDANKEN, A

机构：

[1] Department of Chemistry, Bar-Ilan University, Ramat Gan

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 188卷 / 5-6期

关键词：

D O I：

10.1016/0009-2614(92)80834-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This paper describes new apparatus capable of measuring direct absorption of cold molecular beams down to 1300 angstrom. The absorption of supersonically expanded CS2 was measured in the wavelength region 1620-1460 angstrom. The bands in the 1540-1480 angstrom region are all broad and predissociated and did not show any cooling effect. Four origins associated with excitations to Rydberg d states were assigned.

引用

页码：383 / 387

页数：5

共 13 条

[1] VACUUM ULTRAVIOLET-ABSORPTION SPECTROSCOPY IN SUPERSONIC EXPANSIONS [J].

AMIRAV, A ;

JORTNER, J .

JOURNAL OF CHEMICAL PHYSICS, 1985, 82 (09) :4378-4379

[2] TUNING OF THE FERMI RESONANCE OF CO2 AND CS2 BY TEMPERATURE, PRESSURE, AND MATRIX MATERIAL [J].

BIER, KD ;

JODL, HJ .

JOURNAL OF CHEMICAL PHYSICS, 1987, 86 (08) :4406-4410

[3] HIGHER ELECTRONIC EXCITED-STATES OF CARBON-DISULFIDE - AN ELECTRON-IMPACT INVESTIGATION [J].

DOERING, JP ;

MCDIARMID, R .

JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (10) :1822-1829

[4] MAGNETIC CIRCULAR-DICHROISM OF CARBON-DISULFIDE IN THE REGION OF THE PI-] 4P RYDBERG TRANSITIONS [J].

GEDANKEN, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (21) :5862-5863

[5] NEW INSTRUMENT FOR CIRCULAR-DICHROISM MEASUREMENTS IN VACUUM ULTRAVIOLET [J].

GEDANKEN, A ;

LEVY, M .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1977, 48 (12) :1661-1664

[6] THE DIRECT ULTRAVIOLET-ABSORPTION SPECTRUM OF THE 1-SIGMA-G+-]1B2(1-SIGMA-U+) TRANSITION OF JET-COOLED CS2 [J].

HEMLEY, RJ ;

LEOPOLD, DG ;

ROEBBER, JL ;

VAIDA, V .

JOURNAL OF CHEMICAL PHYSICS, 1983, 79 (11) :5219-5227

[7] STUDY OF CS2 IN THE 3-10 EV ENERGY-RANGE BY ELECTRON-ENERGY LOSS SPECTROSCOPY [J].

HUBINFRANSKIN, MJ ;

DELWICHE, J ;

POULIN, A ;

LECLERC, B ;

ROY, P ;

ROY, D .

JOURNAL OF CHEMICAL PHYSICS, 1983, 78 (03) :1200-1212

[8] ON THE 1593-A TRANSITION OF CS2 [J].

MCDIARMID, R ;

DOERING, JP .

JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (04) :2010-2015

[9] The absorption spectra of sulphur dioxide and carbon disulphide in the vacuum ultra-violet [J].

Price, WC ;

Simpson, DM .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1938, 165 (A921) :0272-0291

[10]

RABALAIS JW, 1971, CHEM REV, V71, P73

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