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PREPARATION OF MULTIPHASE BLOCK-COPOLYMERS BY REDOX POLYMERIZATION PROCESS .2. POLYMERIZATION OF ACRYLONITRILE BY THE MN(III)-POLY(ETHYLENE GLYCOL) REDOX SYSTEM

被引：14
作者：
CAKMAK, I
机构：
[1] Karadeniz Technical University, Department of Natural Sciences Education, Trabzon, 61335, Sogutlu
来源：
ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1993年 / 211卷
关键词：
D O I：
10.1002/apmc.1993.052110105
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Redox polymerization of acrylonitrile (AN) with poly(ethylene glycol) using Mn(III) as catalyst was carried out to yield poly(ethylene glycol-block-acrylonitrile). The principal parameters (concentration of reactants, temperature) affecting the synthesis were examined. Successful blocking has been confirmed by infrared and H-1 nuclear magnetic resonance spectroscopy as well as gel permeation chromatography.
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页码：53 / 60
页数：8
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